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[Yamani]

Can you define Early afternoon as its coming on Mid afternoon now?

Depends on when evening starts! 12-6 could be afternoon which would make 12-2 early, 2-4 mid, 4-6 late aternoon. Then there is evening which is really only 2 hours then its night.
But it could be SSG afternoon which would be anywhere from 12-12 in the literal sense of after noon. So early afternoon could be 12-5/6