Greater Dispel (proc version) effect currently exists on 2 items the upgraded version of Vile Blasphemy which carries the Guard effect "Greater Dispel Guard" the other is Divine Vengeance which carries the weapon proc effect "Greater Dispelling" both cast the same Greater Dispel Magic but they cast it at level 1
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This means that the effect does not work against spells cast by casters level 9 or higher.
Divine Vengeance's Greater Dispelling effect only comes out on a level 20 Paladin... why? The Guard only appears on level 13 item that drops in a level 17 hard using parts that only drop on hard. Makes me think perhaps this affect is not working as intended